WebThe swelling is shown as a ratio of volumes which is identical to 1/φ 2 which is the concentration of polymer in the swollen gel. Check your intuitions about the effect of the measure of "happiness" (the Flory-Huggins χ where 0.5 is starting to be unhappy) and the sizes of the polymer and solvent. The density of the polymer, ρ 2 play a minor ... Web512 P. J. FLORY AND J. REHNER, JR. Equation (12) was used to find the curves shown in Fig. 1. The rate expression involving the acid chro mate ion is -d(Cr03)/dt = k(HCr04-) (CH3CHOHCH3) (H+)2. (6) The concentration of acid chromate ion can be calculated from the equilibrium expression where the parentheses indicate concentrations,
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http://www.physics.emory.edu/faculty/roth/polymercourse/historical/Flory_JCP43.pdf In polymer science Flory–Rehner equation is an equation that describes the mixing of polymer and liquid molecules as predicted by the equilibrium swelling theory of Flory and Rehner. It describes the equilibrium swelling of a lightly crosslinked polymer in terms of crosslink density and the quality of the solvent. The … See more The Flory–Rehner theory gives the change of free energy upon swelling of the polymer gel similar to the Flory–Huggins solution theory: The theory … See more • Flory, Paul; Rehner, John (1943). "Statistical mechanics of cross-linked polymer networks II. Swelling". J. Chem. Phys. 11 … See more inches to cfs
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Web522 P. J. FLORY AND J. REHNER, JR. bining these, there is obtained the total entropy of mixing of solvent with cross-linked polymer, from which activities of solvent and the swelling limit can be computed, as well as their depend ence on the structure of the network. THE ENTROPY OF SWELLING Paralleling the procedure followed in the pre Webフローリー‐レーナーの式【Flory-Rehner equation】. 架橋高分子ゲルの 膨潤 に関する理論式である.膨潤平衡に達したゲル相中の高分子の容積分率を v2 ,高分子溶媒相互作用定数を χ 1 ,溶媒の 分子容 を V1 ,高分子の 比容 を v ,架橋点間の 分子量 を Mc ... Web高分子化学教案逐步聚合copolymerization.docx 《高分子化学教案逐步聚合copolymerization.docx》由会员分享,可在线阅读,更多相关《高分子化学教案逐步聚合copolymerization.docx(15页珍藏版)》请在冰豆网上搜索。 inches to cfm